Mr. Emrick Northwestern High School AP Chemistry/CITC Chemistry

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Mr. Emrick

AP Chemistry/CITC Chemistry through Clark State Community College

Northwestern High School

2012-2013 School Year

Introduction:

The Advance Placement (AP) Chemistry/ CITC Chemistry through Clark State Community College course at Northwestern High School is a first-year college chemistry course taught on campus here at Northwestern High School. The students in this class have two options upon successful completion of the course. In May of 2011, students may take the AP Chemistry exam provided by the College Board Testing Services (approximately $80). The test is scored by the College Board and the score is sent to the colleges or universities indicated by the individual student. College credit may be awarded, at the discretion of the college or university, for a good score on the test. The students may also enroll at Clark State Community College and, at minimal cost and upon successful completion of the course, receive college credit. Class starts at 7:15 and unless you have prior permission, you will be counted tardy after that time.

2012-2013 Syllabus - 1 st Semester

Textbook

Chapters

Power Points

Problem

Sets

Associated

Labs

Topic

Measurements in Chemistry

Atomic Theory and Basic

Nomenclature and

Stoichiometry

Subtopics

Units

Significant

Figures

Objectives

Perform basic calculations related to laboratory measurement by:

Utilizing the correct metric units and convert these values to other units.

 Applying the rules for significant figures to calculation involving measurements.

 Defining and applying the terms, accuracy and precision, to laboratory measurements.

History of Atomic

Theory

Isotopes

Atomic Masses

Empirical and

Molecular

Formulas

Waves

Light

Electronic

Structure

Quantum

Numbers

The Orbital

Electron

Configuration

Atomic and Ionic

Radii

Ionization Energy

Electron Affinity

Electronegativity

Nomenclature

Stoichiometry

Describe atomic and molecular structure on various levels by:

Describing and explaining Dalton's atomic theory and its predictions.

Listing the subatomic particles and their properties.

 Describe the evidence for Quantum Theory and its implications; be familiar with quantum numbers.

Define the chemical mole and perform gram to mole and mole to gram conversions by:

 Applying the mole concept in the following situations: stoichiometric calculations,

 determining empirical and molecular formulas.

Predicting atomic structure and physical/chemical properties of elements using the periodic table.

Explain the reasoning behind the development of the periodic table by:

 Utilizing the periodic table to predict charges of monatomic ions, formulas of ionic compounds, electron configurations of atoms and ions.

Demonstrating knowledge of basic chemical and physical properties of the main group elements by group.

 Making predictions of relative properties of elements utilizing periodic trends.

Utilize chemical equations to describe and explain chemical reactivity by:

 Writing balanced chemical equations.

 Performing calculations using the mole concept in a variety of applications.

Chapter 1

Chapters 2, 3, and 7

Significant

Figures

Unit 1:

Lectures 1, 2,

3, 4, and 5

None All

Problem

Sets:

1, 2, 3, 4, and 5.

Problems from

Textbook

Lab 1

Determination of the

Chemical

Formula of

Magnesium

Oxide

Lab 2

Determination of the Formula of a Hydrate

Lab 3

Analytical

Gravimetric

Determination:

Percentage of

Phosphate in

Plant Food

2012-2013 AP Chemistry Syllabus - 1 st Semester (cont.)

Topic

Chemical

Bonding

Aqueous

Solutions and

Chemical

Reactions

Subtopics

Octet Rule

Ionic Bonding

Lattice Energy

Covalent Bonding

Lewis Diagrams

Exception to the

Octet Rule

Formal Charge

Bond Energy and

Bond Length

Resonance

Structures

Molecular Shapes

VSEPR Theory

Valence Bond

Theory

Hybrid Orbital

Theory

Multiple Bonds

Polar and Non-

Polar molecules

Electrolytic

Solutions

Solubility

Precipitation

Reactions

Redox Reactions

Oxidations

Numbers

Redox Reactions in

Acid and Basic

Solutions

The Activity Series

Halogen

Displacement

Reactions

Hydrogen

Displacement

Reactions

Disproportionation

Reactions

Synthesis Reactions

Decomposition

Reactions

Combustion

Reactions

Objectives

Determine molecular geometry from formulas of compounds by:

 Determining the number of valence electrons in molecules and polyatomic ions from their formulas using the periodic table.

 Drawing Lewis structures of molecules and polyatomic ions from their formulas.

 Determining the shapes of molecules and polyatomic ions from Lewis structures and models utilizing VSEPR concepts.

Explain and apply bonding theories by:

 Describing Valence-Bond Theory and its limitations.

Knowing the relationship between the various molecular geometries and hybridized orbitals.

 Describing the evidence for and the basic concepts of Molecular Orbital Theory and its implications.

 Utilizing MO theory to make predictions of magnetic properties and stability of small molecules/ions.

Utilize chemical equations to describe and explain chemical reactivity by:

Writing balanced chemical equations.

Writing ionic equations and predicting reaction outcomes for precipitation and acid-base reactions.

 Balancing oxidation-reduction reactions.

Performing calculations using the mole concept in a variety of applications.

Textbook

Chapters

Chapters 7, 8, and 9

Chapters 3 and

4

Power Points

Unit 3:

Lectures 10,

11, and 12

Problem

Sets

Associated

Labs

Unit 2:

Lectures 6, 7,

8, and 9

MO Theory

Power Point

Problem

Sets:

6, 7, 8, and 9

Problems from

Textbook

Line Spectra of Hydrogen

Problem

Sets:

10, 11, and 12

Problems from

Textbook

Lab 4

Mass – Mole

Relationship in a chemical

Reaction:

Precipitation of

Calcium

Carbonate

Lab 5

Standardization of Potassium

Permanganate

Solution Using a Primary

Standard, and

Determination of the

Concentration of Hydrogen

Peroxide in a

Solution

2012-2013 - AP Chemistry Syllabus - 1 st Semester (cont.)

Topic

Thermodynamics

Subtopics

Enthalpy

Calorimetry

Hess’s Law

Enthalpy of

Formation

Bond Energy

Entropy

Free Energy

Objectives

Explain and apply the first 2 laws of thermodynamics by:

 Describing and explaining the implications of the First Law of

Thermodynamics.

 Describing and explaining the implications of the Second Law of

Thermodynamics in terms of phase changes and chemical reactions.

Calculating work done in pressure-volume situations.

 Defining enthalpy.

 Calculating specific and molar heat capacities and energy changes involving these quantities.

Define the chemical mole and perform gram to mole and mole to gram conversions by:

 Applying the mole concept in the following situations: stoichiometric calculations, determining empirical and molecular formulas.

Demonstrate understanding of Hess's Law and Gibbs free energy by:

*Calculating heats of reactions utilizing Hess's law and individual reaction steps, bond dissociation energies, or standard heats of formation.

 Defining entropy and Gibbs free energy.

 Making predictions as to whether a process is spontaneous based upon general enthalpy and entropy values.

Textbook

Chapters

Chapters 6 and

16

Power Points

Unit 4:

Lectures 13 and 14

Problem

Sets

Associated

Labs

Problem

Sets:

13 and 14

Problems from

Textbook

Computer Lab

13

Determining the Enthalpy of a Chemical

Reaction

Gases

Pressure

Gas Laws

Ideal Gas Law

Partial Pressures

Mole Fractions

Average KE of a

Gas

Average Speed of a Gas

Effusion

Diffusion

Real vs. Ideal

Gases

Describe and apply the various gas laws by:

 Describing the Boyle's Law, Charles' Law, Graham's Law, Avogadro's Law and the

Ideal Gas Law;

 Applying these laws in calculations of pressure, volume, temperature and mass of gases in changing situations;

Explaining the gas laws using the Kinetic Molecular Theory of Matter.

Chapter 5

Unit 6:

Lectures 18,

19, and 20

Problem

Sets:

18, 19, and 20

Problems from

Textbook

Lab 9

Determination of Molar Mass by Vapor

Density:

Finding the

Molar Mass of

Butane

Lab 10

Determining the Molar

Volume of a

Gas: Finding the Molar

Volume of

Oxygen in a

Reaction

Between

Bleach and

Hydrogen

Peroxide

2012-2013 - AP Chemistry Syllabus - 1 st Semester (cont.)

Topic

Nuclear

Chemistry

Subtopics

Modes of Nuclear

Decay

Configurations for Nuclear

Stability

Binding Energy

Nuclear Fission

Nuclear Fusion

Objectives

Demonstrate understanding of basic nuclear chemistry by

 Describing spontaneous nuclear reactions including balancing nuclear equations and calculating energy changes associated with nuclear reactions

 Listing & describing the 5 ways in which chemical and nuclear reactions differ.

Applying the concepts of nuclear chemistry to define and apply: the radioactive half-life concept of radioactive decay, nuclear transmutation &

 its purpose, and the uses of nuclear chemistry in electricity production, dating (geological, anthropological, archeological), medical diagnosis and basic research.

Using the band of stability to predict and explain what type of radioactivity

(if any) a particular isotope will emit.

Calculating mass defect and binding energies for formation of nuclei.

Describing nuclear fusion and nuclear fission, including the components of a nuclear reactor

Textbook

Chapters

Chapter 18

Power Points

Problem

Sets

Associated

Labs

Unit 13:

Lecture 36

Nuclear

Reactor Power

Point

Problem

Set:

36

Problems from

Textbook

To Be

Determined

Assessment:

Every Topic will have one or more worksheet(s) to practice and assess acquisition of skills and applications of knowledge. These will be reviewed one day after the completion of the topic and subtopics covered in the worksheets. There will be no grade for these worksheets but to pass quizzes and tests you must complete these worksheets prior to their review. Try putting something down in writing on every question on the worksheet. It is OK to miss questions and learn from your mistakes.

Not trying a question at all is not OK.

There will be at least 12 to 15 short, 30-minute quizzes. You will be given exactly 30 minutes to take the quiz. There will be no extended time for the quiz, so don’t ask.

The quiz will cover recently completed lectures. Each quiz is worth 10 points.

At the end of each Unit there will be a period long test. The test will begin promptly at 7:15 and will be collected at 8:15. You will be given exactly one hour to take the test. There will be no extended time for the test, so don’t ask. The tests will vary from 20 to 30 points.

You will be taking a mid-semester exam at the end of the 1 st quarter. The test will be given over two days and will begin at 7:15 and end at 8:15. You will be given exactly one hour each day to take the exam. There will be no extended time for the exam, so don’t ask. Each exam will be a combination of multiple choice (day 1) and free response questions (day 2) from the first quarter. The exam will be 50 points.

There will be a semester exam given before winter break. The exam will begin promptly at 7:15 and end at 8:45. The exam will be a combination of multiple choice and free response questions from the first semester. The exam will be 100 points.

There are two different types of lab reports. o Formal labs reports (one each quarter) are typed, are worth 50 points (5 points for each bullet), and will include:

 title page (experiment title, your name, your partner’s name, date of lab, date of report, instructor)

 abstract of lab at the bottom of the title page

 purpose of the lab

 introduction that relates purpose to chemistry concepts

 summary of procedure

 data tables

 calculations

 analysis of data and calculations including error analysis

 summary of results of analysis as related to purpose

 pre-lab questions with answers o Informal lab report (those not assigned as formal) are worth 20 points (4 points for each bullet) and will include:

 pre-lab questions with answers

 data table(s)

 calculations

 analysis

 summary

Your grade for each quarter will be based on percentage of total points earned. See your agenda for letter grade.

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