Nitrogen, Refrigerated Liquid

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DISTRIBUTED BY: Josef Gas.

M A T E R I A L S A F E T Y D A T A S H E E T

PRODUCT IDENTIFIER:

NITROGEN, REFRIGERATED LIQUID

Product Name(s): Nitrogen, Refrigerated Liquid Formula: N2

Synonym(s): LN2 Chemical Family: ELEMENT

PRODUCT USE(S): Purging and filling of electronic W.H.M.I.S. Classification

Devices, high-voltage compression Class(es): A cables. Blanketing atmosphere de-aeration of oxygen sensitive liquids.

HAZARDOUS INGREDIENTS:

INGREDIENT

PARAMETERS

NITROGEN

C.A.S. / P.I.N.

NUMBER(S)

CONC. %

VOL./VOL.

7727379/1977 APPR. 100

L.D. 50 L.C. 50

(Species & Route) (Species & Route)

NOT APPL. NOT APPL.

PHYSICAL STATE:

ODOUR AND APPEARANCE:

ODOUR THRESHOLD:

SPECIFIC GRAVITY (air=1):

VAPOUR PRESSURE:

VAPOUR DENSITY:

EVAPORATION RATE:

BOILING POINT:

FREEZING POINT: pH:

PHYSICAL DATA

Gas @ N.T.P.

Colourless and Odourless

NONE

0.808 (@ Boiling Point)

Container Rated Pressure

0.967

Rapid

-195.8

o C (-320.4

o F)

-209.8

o C (-345.7

o F)

Not Applicable

COEFFICIENT OF WATER/OIL DISTRIBUTION:

SOLUBILITY IN WATER:

% VOLATILES:

Not Applicable

0.023 (vol./vol.)

100

FOR TRANSPORT EMERGENCY CALL COLLECT CANUTEC TEL: 1-613-996-6666

UYI 110-2

FIRE OR EXPLOSION HAZARDS

CONDITIONS OF FLAMMABILITY:

MEANS OF EXTINCTION:

FLASH POINT: NONE

UPPER FLAMMABLE LIMIT: NONE

AUTOIGNITION TEMPERATURE:

HAZARDOUS COMBUSTION PRODUCTS:

SENSITIVITY TO MECHANICAL IMPACT:

SENSITIVITY TO STATIC DISCHARGE:

SPECIAL PROCEDURES:

NONE. Nitrogen will not support or sustain combustion of other materials.

Cool containers with water spray. Extinguish surrounding fire(s).

LOWER FLAMMABLE LIMIT: NONE

NONE

NONE

NONE

NONE

Evacuate areas where a leak or a spill is present. Extinguish surrounding fires. DO NOT use water on the source of the leak as to avoid ice formation that may obstruct the operation of the Safety

Relief Device.

REACTIVITY DATA

CONDITIONS OF CHEMICAL UNSTABILITY: NONE

INCOMPATIBILITY: Cool liquid may embrittle some materials

CONDITIONS OF REACTIVITY: NONE

HAZARDOUS DECOMPOSITION PRODUCTS: NONE

TOXICOLOGICAL PROPERTIES

ROUTE OF ENTRY

SKIN (CONTACT):

SKIN (ABSORPTION):

EYE CONTACT:

INHALATION:

YES

NO

YES

YES

INGESTION: YES

EFFECTS OF ACUTE EXPOSURE:

May displace air in enclosed spaces. If oxygen concentration falls below 18% symptoms of asphyxia may develop.

Symptoms may include: nausea, dizziness, unconsciousness, convulsions, coma and death.

EFFECTS OF CHRONIC EXPOSURE:

EXPOSURE LIMITS:

IRRITANCY:

SENSITIZATION:

CARCINOGENICITY:

REPRODUCTIVE TOXICITY:

TERATOGENICITY:

MUTAGENICITY:

TOXIC SYNERGISTIC PRODUCTS:

NONE KNOWN

Maintain ambient oxygen concentration above 18%

NONE

NONE

NONE

NONE

NONE

NONE

NONE

UYI 110-3

FIRST AID

EYE:

INGESTION:

INHALATION:

For frostbite rinse with warm water for 15 minutes. Obtain medical attention immediately.

Maintain breathing. Obtain medical attention immediately.

Move victim to fresh air if possible. Administer C.P.R. if breathing has stopped. If breathing is difficult give oxygen. Obtain medical attention.

For frostbite, allow effected body parts to thaw. Obtain medical attention. SKIN:

PREVENTIVE MEASURES

PERSONAL PROTECTION

EYE:

HAND:

FEET:

CLOTHING:

Full faceshield to prevent contact with cold liquid

Insulated Work gloves

Safety footwear where applicable.

Long sleeves, trousers recommended.

RESPIRATOR: Not applicable where oxygen concentration is kept above 18%.

ENGINEERING CONTROLS: Provide ventilation. Keep oil, grease, and combustible materials away.

SPILL AND LEAK PROCEDURE:

Leave danger area. Try to stop the leak at source if without risk. Gas will dissipate depending on the site/area ventilation. Verify oxygen concentration prior to re-entry.

WASTE DISPOSAL:

No wastes may be generated other than empty containers. Return empty containers as the case may be. Disposal of waste containers must be done in accordance with Federal, Provincial and Municipal regulations.

HANDLING PROCEDURES & EQUIPMENT:

Use only in well ventilated areas. Use only with regulating equipment designed for Nitrogen service and source pressure. Use appropriate carts for moving containers.

Secure container when not in use. Close the container valve when NOT in use, or when empty.

STORAGE REQUIREMENTS:

Store in well ventilated areas. Keep containers upright. Protect containers from physical damage. Segregate full and empty containers. Replace cap on container, if applicable.

SPECIAL SHIPPING INFORMATION:

Transport upright in well-ventilated vehicle. Do not transport in trunk of enclosed vehicle. Commercial quantities

(cylinders) may NOT be transported in passenger compartments.

T.D.G. SHIPPING NAME: Nitrogen, Refrigerated Liquid T.D.G. CLASSIFICATION CLASS(ES):

T.D.G. P.I.N. / U.N. : 1977

PREPARED BY:

TEL:

EFFECTIVE DATE:

Josef Gas.

(416) 658-1212

August 2014

2.2

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