ELENCO PUBBLICAZIONI

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ELENCO DELLE PUBBLICAZIONE E DEI BREVETTI DEL PROF. G. CAVINATO
83) E. Negro, S. Polizzi, K. Vezzù, L. Toniolo, G. Cavinato, V. Di Noto. Interplay between
morphology and electrochemical performance of “core–shell” electrocatalysts for oxygen
reduction reaction based on a PtNix carbon nitride “shell” and a pyrolyzed polyketone
nanoball “core”. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, (2014)28282841.
82) V. Di Noto, E. Negro, S. Polizzi, K. Vezzù, L. Toniolo, G. Cavinato. Synthesis, studies
and fuel cell performance of “core–shell” electrocatalysts for oxygen reduction reaction based
on a PtNix carbon nitride “shell” and a pyrolyzed polyketone nanoball “core”.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 39 (2014)2812-2827.
81) E. Amadio, G. Cavinato, P. Harter, L. Toniolo. An NMR study on the mechanism of
ethene hydromethoxycarbonylation catalyzed by cationic Pd(II)-PPh3 complexes. JOURNAL
OF ORGANOMETALLIC CHEMISTRY, 745-746 (2013)115-119.
80) L. Calore, G. Cavinato, P. Canton, L. Peruzzo, R. Banavali, K. Jerabek, B. Corain
Metal catalysis with nanostructured metals supported inside strongly acidic cross-linked
polymer frameworks. Influence of reduction conditions of Au(III)-containing resins on metal
nanoclusters formation in macroreticular and gel-type materials.
Inorganica Chimica Acta, 391(2012)114-120.
79) Sartori Andrea, El Habra Naida, De Zorzi Chiara, Sitran Sergio, Casarin Maurizio, Cavinato
Gianni, Sada Cinzia, Gerbasi Rosalba, Rossetto Gilberto
Zirconocene Alkoxides, Promising Precursors for MOCVD of Zirconium Dioxide Thin Films
Chemical Vapor Deposition, 18(4-6)(2012)151-158.
78) G. Cavinato, S. Facchetti, L. Toniolo
Oxidative carbonylation of ethene catalyzed by Pd(II)-PPh3 complexes in MeOH using
benzoquinone as stoichiometric oxidant.
Journal of Molecular Catalysis A: Chemical, 352(2012)63-69.
77) Vito Di Noto, Matteo Piga, Guinevere A. Giffin, Micheal Sschuster, Gianni Cavinato, Luigi
Toniolo, Stefano Polizzi
New Sulfonated Poly(p-phenylenesulfone)/Poly(1-oxotrimethylene) Nanocomposite ProtonConducting Membranes for PEMFCs.
Chemistry of Materials, 23 (2011)4452-4458.
76) Calore L., Cavinato G., Canton P., Peruzzo L., Tauro L., Corain B.
Metal catalysis with nanostructured metals supported on strongly acidic cross-linked polymer
frameworks. Part I. The behaviour of M2+ ions (M = Ni, Pd, Pt, Cu) supported on Rohm &
Haas's resin A70 and Du Pont's SAC-13, towards H2 in the solid state and NaBH4 in aqueous
medium.
Reactive & Functional Polymers, 70(2010)639-646.
75) Gianni Cavinato, Sarah Facchetti, Luigi Toniolo
Ethene hydromethoxycarbonylation catalyzed by cis-[Pd(SO4)(PPh3)2]/H2SO4/PPh3.
Journal of Molecular Catalysis A: Chemical, 333(2010)180-185.
74) Calore L., Cavinato G., Canton P., Peruzzo L., Tauro L., Corain B.
Metal catalysis with nanostructured metals supported on strongly acidic cross-linked polymer
frameworks. Part I. The behaviour of M2+ ions (M = Ni, Pd, Pt, Cu) supported on Rohm &
Haas's resin A70 and Du Pont's SAC-13, towards H2 in the solid state and NaBH4 in aqueous
medium.
Reactive & Functional Polymers, 70(2010)639-646.
73) Amadio E., Cavinato G., Dolmella A., Toniolo L.
Catalytic Properties of [Pd(COOMe)nX(2-n)(PPh3)2] (n=0, 1, 2; X = Cl, NO2, ONO2,
OAc and OTs) in the Oxidative Carbonylation of MeOH.
Inorganic Chemistry, 49(2010)3721-3729.
72) Vavasori A., Dall'Acqua F., Cavinato G., Toniolo L.
Influence of the operating conditions on the catalytic activity of [PdCl2(dapp)] in the CO-ethene
copolymerization in the H2O-CH3COOH as a solvent (dapp = 1,3-bis(di(2-methoxyphenyl)
phosphino)propane).
Journal of Molecular Catalysis A: Chemical. 332(2010)158-164.
71) Vavasori A., Ronchin L., Amadio E., Toniolo L., Cavinato G.
Terpolymerisation of 1-olefin and ethene with CO catalysed by the [PdCl2(dppp)] complex in
methanol as a solvent[dppp= 1,3-bis(diphenylphosphino)propane].
Journal of Molecular Catalysis A: Chemical, 299 (2009)5-11.
70) Ronchin L., Vavasori A., Bernardi D., Cavinato G., Toniolo L.
Selective hydrogenation of ethyl-benzoylacetate to 3-hydroxy-3-phenyl-propionate catalyzed by
Pd/C in EtOH as a solvent in the presence of KOH: The role of the enolate ion on the reaction
mechanism.
Applied Catalysis A: General, 355(2009)50-60.
69) Ronchin, L., Vavasori, A., Amadio E., Cavinato G., Toniolo L.
Oxidative carbonylation of phenols catalyzed by homogeneous and heterogeneous Pd
precursors.
Journal of Molecular Catalysis A: Chemical, 298(2009)23-30.
68) Ronchin L., Vavasori A., Bernardi D., Cavinato G., Toniolo L.
Selective hydrogenation of ethyl-benzoylacetate to 3-hydroxy-3-phenyl-propionate catalyzed by
Pd/C in EtOH as a solvent in the presence of KOH: The role of the enolate ion on the reaction
mechanism.
Applied Catalysis A: General, 355(2009)50-60.
67) Amadio E., Cavinato G., Dolmella A., Ronchin L., Toniolo L., Vavasori A.
New carboalkoxybis(triphenylphosphine)palladium(II) cationic complexes: Synthesis,
characterization, reactivity and role in the catalytic hydrocarboalkoxylation of ethene. X-ray
structure of trans-[Pd(COOMe)(TsO)(PPh3)2]·2CHCl3.
Journal of Molecular Catalysis A: Chemical, 298(2009)103-110.
66) G. Carta, N. El Habra, G. Rossetto, L. Crociani , G. Torzo, P. Zanella, M. Casarin, G. Cavinato,
G. Pace, S. Kaciulis, A. Mezzi
Chemical vapor deposition of hafnium dioxide thin films from cyclopentadienyl hafnium
Compounds.
Thin Solid Films, 516(2008)7354-7360.
65) G. Carta, N. El Habra , G. Rossetto, G. Torzo, L. Crociani , M. Natali, P. Zanella,
G. Cavinato, V. Matterello, V. Rigato, S. Kaciulis, A. Mezzi
Growth of hafnium dioxide thin films by MOCVD using a new series of cyclopentadienyl
hafnium compounds.
Chemical Vapor Deposition, 13 (2007) 626-632.
64) G. Carta, G. Rossetto, F. Benetollo, P. Zanella, G. Cavinato
Synthesis and physico-chemical characterization of [Hf(NEt2)2Cl2(DME)] and it use as catalyst
for ethylene polymerization.
Inorganic Chemistry Communications, 110(2007)930-932.
63) Vavasori A., Bellini L., Ronchin L., Dall’Acqua F., Toniolo L., Cavinato G.
Selective copolymerisation of carbon monoxide and ethene catalysed by [PdCl2(dppf)]
in acetic acid-water as a solvent [dppf = 1,1’-bis(diphenylphosphino)ferrocene].
Journal of Molecular Catalysis A: Chemical 263(2007)9-14.
62) G. Cavinato, A. Vavasori, E. Amadio, L. Toniolo
CO-ethene copolymerisation catalysed by [PdCl2(PPh3)2]/PPh3/HCl in MeOH.
Journal of Molecular Catalysis A: Chemical 278(2007)251-257.
61) G. Cavinato, L. Toniolo, A, Vavasori
Carbonylation of ethene in methanol catalysed by cationic phosphine complexes of Pd(II): from
polyketones to monocarbonylated products.
Topics in Organometallic Chemistry, 18(2006)124-164.
60) G. Cavinato, A. Vavasori, L. Ronchin, F. Dall’Acqua, A. Dolmella
Synthesis, characterization and X-ray structure of [Pd(SO4)(dppp)]·H2O, a catalyst for the COethene copolymerisation [dppp = 1,3-bis(diphenylphosphino)propane].
Inorganica Chimica Acta, 358(2005)4555-4562.
59) G. Cavinato, A. Vavasori, L. Toniolo, A. Dolmella
Synthesis, characterization and catalytic activity in the carbonylation of ethene of
cis-[Pd(H2O)2(PPh3)2]X2·nH2O(X = p-CH3C6H4SO3, n = 2; X = CH3SO3, n = 0).
X-ray structure of cis-[Pd(H2O)2(PPh3)2]( p-CH3C6H4SO3)2·2H2O and of
cis-[Pd(H2O)2(PPh3)2](CH3SO3)2·2CH2Cl2.
Inorganica Chimica Acta, 357 (2004 )2737-2747.
58) G. Cavinato, A. Vavasori, L. Toniolo
Characterization and catalytic activity of trans-[Pd(COCH2CH3)(TsO)(PPh3)2], isolated from
the hydro-methoxycarbonylation of ethene catalysed by [Pd(TsO)2(PPh3)2],
J. Mol. Catal. Chem. A, Chemical, 219(2004)233-240.
57) F. Benetollo, G. Carta, G. Cavinato, L. Crociani, G. Paolucci, G. Rossetto, F. Veronese,
P. Zanella
New η2-Formamidinyl Zirconium Complexes: Synthesis, Characterization and Catalytic
Activity.
Organometallics, 22(20) (2003) 3985-3990.
56) A. Vavasori, L. Toniolo, G. Cavinato
Carbon monoxide-ethylene copolymerisation catalysed by [PdCl2(dppp)] in methanol-water or
in acetic-water as solvents (dppp = 1,3-bis(diphenylphosphine)propane).
J. Mol. Catal. Chem. A, Chemical, 215 (2003) 63-72.
55) G. Cavinato, A. Vavasori, L. Toniolo, F. Benetollo
Synthesis, characterization and X-ray structure of trans-[Pd(COOCH3)(H2O)(PPh3)2](TsO), a
possible intermediate in the catalytic hydroesterification of olefins ( TsO = p-toluensulfonate).
Inorg. Chim. Acta, 343 (2003) 183-188.
54) A. Vavasori, L. Toniolo, G. Cavinato, F. Visentin
Highly active [Pd(AcO)2(dppp)] catalyst for CO-C2H4 copolymerization in H2O-CH3COOH
solvent [dppp =1,3-bis(diphenylphosphino)propane]
J. Mol. Catal. Chem. A, Chemical, 204-205 (2003) 295-303.
53) A. Vavasori, L. Toniolo, G. Cavinato
Hydroesterification of cyclohexene using the complex Pd(PPh3)2(TsO)2 as catalyst precursor.
Effect of a hydrogen source (TsOH, H2O) on the TOF and a kinetic study ( TsOH: p-toluene
sulfonic acid).
J. Mol. Catal. Chem. A, Chemical, 191 (2003) 9-21.
52) A. Vavasori, G. Cavinato and L. Toniolo
Carbon Monoxide-Ethylene Copolymerization Catalyzed by a Pd(OAc)2/Dppp/Fornic Acid
System [dppp=1,3-bis(diphenylphosphino)propane].
J. Mol. Catal. Chem. A, Chemical, 191 (2003) 209-215.
51) G. Carta, G. Rossetto, P. Zanella, S. Battaini, S. Sitran, P. Guerriero, G. Cavinato, L. Armelao,
E.Tondello
Synthesis and characterization of metal oxide multilayers obtained via MOCVD as protective
coatings of graphite against oxidation.
Surface and Coatings Technology,160 (2002)124-131.
50) G. A. Battiston, G. Carta, G. Cavinato, R. Gerbasi, M. Porchia and G. Rossetto
MOCVD of Al2O3 Films Using New Dialkylaluminium Acetylacetonate Precursors: Growth
Kinetics and Process Yields.
Chemical Vapor Deposition, 7 (2001) 69-74.
49) A. Vavasori, G. Cavinato, L. Toniolo
Effect of Hydride Source ( Water, Hydrogen, p-Toluensolfonic acid) on the Hydroesterification
of Ethylene to Methyl Propinate Using a Pd(PPh3)2(TsO)2 ( TsO = p-Toluensulfonate anion)
Catalyst Precursor.
J. Mol. Catal. Chem. A, 176 (2001) 11-18.
48) D. Barreca, F Benetollo, M. Bozza, S. Bozza, G. Carta, G. Cavinato, G. Rossetto and
P. Zanella
Metal Organic Chemical Vapor Deposition of Co-, Mn-, Co-Zr And Mn-Zr Oxide Thin Films.
Mat. Res. Soc. Symp. Proc., 606(2000) 69-74.
47) U. Casellato, G. Cavinato R. Graziani and L. Toniolo
Crystal Structure of (cyclohexanonetriphenylphosphonium)(trichlorotriphenyl)palladate(II)benzene(1/1), [(C2H5)3P(CHCH2CO(CH2)3)][(C6H5)3PPdCl3]·C6H6.
Z. Kristallogr. NCS 215 (2000) 377-379.
46) G. Cavinato, L. Toniolo
[PdCl2(PPh3)2]- PPh3 Catalyzed Regiospecific Alkoxycarbonylation of alfa-chloroexylketone
to β-ketoester.
J.Mol. Catal. Chem. A, 143 (1999) 325-330.
45) F. Benetollo, G. Cavinato, L. Crosara, F. Milani, G. Rossetto, C. Scelza, P.Zanella
New O- and N-bonded Zirconocene Complexes and their Catalytic Properties in Ethylene
Polymerization. X-ray Crystal Strutture of (C5H5)2Zr{2,6-OC6H3(CH3)2}2, (C5H5)2Zr{2,4,6
OC6H2(CH3)3}2 and (C5H5)2Zr(CH3){CH(NC6H5)2}.
J. Organomet. Chem., 555 (2) (1998) 77-185.
44) L. Ronchin, L. Toniolo, G. Cavinato
Hydrogenation of Mandelic Acid Derivatives to the Corresponding Phenyl Acetic Acid
Derivative Catalyzed by Pd/C. A kinetic Study.
Applied Catalysis A, 165 (1997) 133-145.
43) G. Cavinato, M. Pasqualetto, L. Ronchin, L. Toniolo
Palladium Catalyzed Hydrodechlorination of α-chloroacetophenones by Hydrogen Transfer
from the H2O-CO System.
J. Mol. Catal. Chem. A, 125 (1997) 15-22.
42) G. Cavinato, L. Toniolo
Highly Selective Transfer Hydrogenation from Formates to the C=C Double Bond of γ-ketoα,β Unsaturated Carboxylic Acids Catalyzed by Pd/C.
J. Mol. Catal. Chem. A, 106 (1996) 25-30.
41) G. Cavinato, L. Toniolo
On the Mechanism of the Hydrogen Transfer from H2O-CO to γ-keto-α-hydroxy Carboxylic
Acid to Yield γ-keto Acids Catalyzed by a PdCl2(PPh3)2 Precursor in Combination with
Hydrochloric Acid.
J. Mol. Catal. Chem.A, 105 (1996) 9-15.
40) G. Cavinato, L. Toniolo
Synthesis of γ-ketocycloalkanecarboxylic Acid Esters by Regiospecific Alkoxycarbonylation
of α,β-ketocycloolefins Catalyzed by Palladium.
J. Mol. Catal. Chem. A, 104 (1996) 221-227.
39) G. Cavinato, L.Ronchin, L. Toniolo
Synthesis of Arylacetic acid Derivatives from Mandelic acid Derivatives by Hydrogen
Transfer from H2O-CO Catalyzed by a Pd/C-HCl System.
J. Mol. Catal., 102(1995)129.
38) G. Cavinato, L. Toniolo, G. Vasapollo, F. Bigoli, M. Lanfranchi, M. A. Pellinghelli
Bis(alkoxycarbonyl) Complexes of Platinum Preparation, Reactivity and their Role in
Carbonylation Reactions.
J. Organomet. Chem., 481(1994)173.
37) G. Cavinato, G. De Munno, M. Lami, M. Marchionna, L. Toniolo and D.Viterbo
Isolation and Characterization of the Acyl Complexes trans-[Pt(PPh3)2(COR)Cl] ( R = nBu or
s
Bu) and their Relevance to the Hydroformylation of Linear Butenes Catalyzed by PlatinumTin- Triphenylphosphine Catalytic Systems. Molecular Structure of cis-[Pt(PPh3)2Cl(SnCl3)].
J. Organomet. Chem., 466 (1994) 277.
36) Cavinato, L. Ronchin, L.Toniolo
Highly Selective Palladium Catalyzed Hydrogrn Transfer from H2O-CO to the C=C Double
Bond of β-benzoylacrylic acid.
J. Mol. Catal., 94 (1994) 173.
35) G. Cavinato, P. Bertani, G. Facchin, L. Toniolo, A. Vavasori
New Aspects of the Carbonylation of Allylpalladium Complexes.
J. Organomet. Chem., 466 (1994)273.
34) Cavinato, L. Toniolo, A. Vavasori
Synthesis of γ-ketocarboxylic Acid via Reduction of γ-keto-α-hydroxycarboxylic Acids with
Carbon Monoxide Catalyzed by Pd-HCl System.
J. Mol. Cata., 89 (1994) 93.
33) R. Bertani, G. Cavinato, L. Toniolo and G.Vasapollo
New Alkoxycarbonyl Complexes of Palladium(II) and Their Role in Carbonylation
Reactions Carried Out in the Presence of an Alkanol.
J. Mol. Catal., 84 (1993) 165-176.
32) G. Cavinato and L. Toniolo
Syntheses of γ-keto Carboxylic Acids from γ-keto-α-chlorocarboxylic Acid via
Carbonylation Decarboxylation Reactions Catalyzed by a Palladium System.
J. Mol. Catal., 78 (1993) 121-129.
31) G. Cavinato and L, Toniolo
Palladium-Catalvzed Carbonylation of Benzvl Alcohol Derivatives to Phenylacetic acid
Derivatives.
J. Mol. Catal., 78 (1993)131-142.
30) G. Cavinato and L. Toniolo
Influence of the Reaction Parameters on the Pd-HCl Catalyzed Synthesis of Phenylacetic
Acid Derivatives via Reduction of Mandelic Acid Derivatives with Carbon Monoxide.
J. Mol. Catal., 78 (1993) 9-20.
29) G. Cavinato and L. Toniolo
New Aspects of the Synthesis of Dimethyl Carbonate via Carbonylation of Methyl Alcohol
Promoted by Methoxvcarbonyl Complexes of Palladium(II).
J. Organomet. Chem,, 444 (1993) C65-C66.
28) G. Cavinato and L Toniolo
Synthesis of Arylacetic Acid Derivatives via Reductive Carbonylation of Mandelic Acid
Derivatives Catalyzed by a Highly Active Pd-HCl System
J. Mol. Catal., 75 (1992) 169.
27) G. Cavinato and L. Toniolo
Carbonilation of Aromatic Aldehydes to Phennylacetic Acid Derivatives Catalyzed by a PdPPh3-HCl System.
J. Mol. Catal., 69 (1991) 283.
26) G. Cavinato, L. Toniolo
On the Mechanism of the Hydrocarbalkoxylation of Olefins Catalyzed by Palladium
Complexes.
J. Organomet. Chem., 398 (1990) 187.
25) G. Cavinato, L. Toniolo
Levulinic Acid Synthesis Via Regiospecific Carbonylation of Methylvinyl Ketone or of its
Reaction Products with Hydrocloric Acid or an Alkanol or of a Mixture of Acetone with a
Formaldheyde Precursor Catalyzed by a Highly Active Pd-HCl System.
J. Mol. Catal., 58 (1990) 251.
24) R. Graziani, G. Cavinato, U. Casellato, L. Toniolo
The Isolation and Molecular Structure of trans-[PtCl(COCH2CH2Ph)(PPh3)2]. EtOH, an
Intermediate in the Hydroformylation of Styrene Promoted by the cis-[PtCl2(PPh3)2]-SnCl2
Catalytic System.
J. Organomet. Chem. 353 ( 1988) 125.
23) R. Bardi, A.M. Plezzesi, A. Del Pra, G. Cavinato and L. Toniolo
Metals in Organic Syntheses XIII. The Isolation and Molecular Structure of
trans-[PdCl(COC6H13-n)(PPh3)2], an Intermediate in the Hydrocarboalkoxylation of
1-Hexene Catelyzed by the Precursor trans-[PdCl2(PPh3)2].
Inorg. Chim. Acta, 102 (1985) 99.
22) G. Cavinato, L. Toniolo, and C. Botteghi,
Meltals in Organic XII. Hydrocarboalkoxylation of Ethyl 3-Butenoate Catalyzed by
Palladium Complexes.
J. Mol. Catal. 32, (1985) 211.
21) A. Scrivanti, G. Cavinato, Toniolo and C. Botteghi
Metals in Organic Syntheses XI. 31P NMR and Reactivity Studies on the System
trans-[PtCl(CO-n-hexyl)(PPh3)2]-SnCl2, an Active Intermediate in the Catalytic
Hydroformylation of 1-hexene.
J. Organomet. Chem., 286 (1985) 115.
20) L. Toniolo, G. Cavinato
Processo per la Preparazione di γ-chetoacidi Chetoni e Acido Gliossilico
Brevetto Italiano n° 23201A/84, CNR 62.
19) L. Toniolo, G. Cavinato
Processo per la Preparazione di γ-chetoacidi da γ-chetoaloacidi
Brevetto Italiano n° 23202A/84, CNR 61.
18) L. Toniolo, G. Cavinato
Processo per la Preparazione di γ-chetoacidi da γ-chetoossiacidi
Brevetto Italiano n° 23200A/84, CNR 60.
17) L. Toniolo, G. Cavinato
Processo per la Preparazione di γ-chetoacidi Saturi da γ-chetoacidi α,β insaturi
Brevetto Italiano n° 23199A/84, CNR 59.
16) L. Toniolo, G. Cavinato
Processo per la Preparazione di γ-chetoacidi da Chetoni
Brevetto Italiano n° 22736A/83, CNR 29.
15) L. Toniolo, G. Cavinato
Processo per la Preparazione di γ-chetoacidi o Chetoesteri
Brevetto Italiano n° 22738A/83, CNR 35.
14) L. Toniolo, G. Cavinato
Processo per la Preparazione di γ-chetoacidi o Chetoesteri
Brevetto Italiano n° 22735A/83, CNR 36.
13) L. Toniolo, G. Cavinato
Processo per la Preparazione di γ-chetoacidi o loro Esteri
Brevetto Italiano n° 22539A/83 CNR 34.
12) G. Cavinato and L. Toniolo
Metals in Organic Syntheses X. Olefin Hydroformylation and Hydrocarboalkoxylation
Competitively Catalyzed by a [PtCl2(PPh3)2]-SnCl2 System.
J. Organomet. Chem., 241 (1983) 275.
11) R. Bardi, A.M. Píazzesi, A. Del Pra, G. Cavinato, and L. Toniolo
Metals in Organic Syntheses IX. The Isolation and Molecular Structare
of trans-[PtCl(COC6H13-n)(PPh3)2 , an Intermediate Precursor in the Catalytic
Hydroformylation of 1-Hexene.
J. Organomet. Chem. , 234 (1982) 107.
10) G. Cavinato, L. Toniolo, C. Botteghi and S. Gladiali
Hydrocarboalkoxylation of N-Vinylphtalimide Catalyzed by Palladiun Complexes.
J. Organomet. Chem., 229 (1982) 93.
9) R. Bardi, A.M. Piazzesi., G. Cavinato, P. Cavoli and L. Toniolo
Metals in Organic Syntheses VII. The Isolation of trans-[Pt(COPr-n)Cl(PPh3)2] (I) and
trans-[Pt(SnCl3)(COPr-n)(PPh3)] (II) , Active Intermediates in the Hydroformylation of
Propene Catalyzed by a [PtCl2(PPh3)2]-SnCl2 Precursor. The Crystal and Molecular Structure
of Complex I and a Comparison with its Palladium Analog.
J. Organomet. Chem., 224 (1982) 407.
8) G. Cavinato and L. Toniolo
Metals in Organic Syntheses VI. The Solvent Effect on the Hydrocarboalkoxylation of
Propene Promoted by a [PdCl2 (PPh3)2]-PPh3 Catalyst Precursor.
J. Mol. Catal., 10 (1981) 161.
7) G. Cavinato and L. Toniolo
Metals in Organic Syntheses II. The Effect of Molecular Hydrogen on the Highly
Regioselective Hydrocarboxylation of Propene Promoted by a [PdCl2(PPh3)2 –PPh3 Catalyst
Precursor.
Chimia, 33 (1979) 28.
6) G. Cavinato and L. Toniolo
The Effect of Molecular Hydrogen on the Highly Regioselective Hydrocarboxylation of
Propene Promoted by dichlorobis(triphenyl phosphine)palladium-triphenyl phosphine as
catalytic precursor.
Atti Congr. Naz. Chim. Inorg. 12th, (1979) 430-2
Chemical Abstract vol 95 (1981) [95:41799x].
5) G. Cavinato and L.. Toniolo
Metals in Organic Syntheses I. Propene Hydrocarboxylation with Various Alkanols and
[PdCl2(PPh3)2] as Catalyst Precursor.
J. Molec. Catal., 6 (1979) 111.
4) R. Bardi, A.M. Piazzesi, A. Del Pra, G. Cavinato and L. Toniolo
Reactivity of Functionalized Halo -Derivatives with Transition Metal Complexes. Synthesis
and X-Ray Diffraction Study of [Ph3P(CH2CH2COCH3)]+ [PdCl(PPh )]- Obtained by Reaction
of trans-[PdCl2(PPh3)2] with CH3COCH2CH2Cl.
Inorg. Chim. Acta, 75 (1983) 15.
3) G. Cavinato and L. Toniolo
Convenient One-Step Synthesis of Substituted Phosphine Complexes of Platinum (II)
Directly from Hexachloroplatinic Acid.
Inorg. Chim. Acta, 52 (1981) 39.
2) L.Toniolo and G. Cavinato
A 1H NMR Study of trans-Hydrido(1,3-diaryltriazenido)bis(triphenylphosphine)platinum(II)
Complexes.
Inorg. Chim. Acta, 26 (1978) L5.
1) L.Toniolo and G. Cavinato
Reactivity of [M(ArN-N=NAr)(CO)(PPh3) with Aryldiazonium Salts
(M=Rh(I), Ir(I); Ar = p-CH3C6H4 , p- FC6H4).
Inorg. Chim. Acta, 35 (1979) L 301.
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