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Ionic Nomenclature

• Must be neutral overall

• NO PREFIXES!!!!!!

• Name the cation first, then the anion

• Cation is either a metal or ammonium

• To name a metal cation, use the element name and a roman numeral to indicate the charge of the cation

• Tin(II) is Sn 2+

• Tin(III) is Sn 3+

• Mercury(II) is Hg 2+

• Mercury(I) is Hg

2

2+ (it’s diatomic)

• Roman numerals are NOT used for the following because they only have one charge: Group 1A (+1), Group 2A(+2), ammonium(+1), or

CdZnAgAl 2213 (where 2 is the charge of Cd, 2 is the charge of Zn, etc.)

• Sodium is Na +

• Magnesium is Mg 2+

• Cadmium is Cd 2+

Ionic Nomenclature

• Anion is either a nonmetal or a negative polyatomic ion

(like sulfate or phosphite)

• Use the ion name for the nonmetal (Cl is chloride)

• Some examples for you to look at before we practice

• Zr(NO

3

)

2

= zirconium(II) nitrate

• Since nitrate has a -1 charge and there are 2 of them, zirconium must have a +2 charge to make the compound neutral overall

• CuCl = copper(I) chloride

• CuCl

2

= copper(II) chloride

• the # of Cl depends on the charge of Cu ion

• Ag

3

PO

4

= silver phosphate (no roman numerals because this is part of CdZnAgAl 2213)

Work with your shoulder partner –

A does #1 and B checks, B does #1 and A checks

A does #2 and B checks, etc.

 the answers will be displayed when everyone is done

These are A’s problems

(B will check them)

1. Au(ClO)

2

2. MgO

3. Fe

2

S

3

4. AlN

These are B’s problems

(A will check them)

1. CoP

2. Ag

2

CO

3

3. Ca(CN)

2

4. PbF

2

If there are groups of 3, just rotate A, B, and C

Hint: each set has 2 that need roman numerals and 2 that do not

Answers

These are A’s problems

(B will check them)

1. Au(ClO)

2 gold(II) hypochlorite

2. MgO magnesium oxide

3. Fe

2

S

3 iron(III) sulfide

4. AlN aluminum nitride

These are B’s problems

(A will check them)

1. CoP cobalt(III) phosphide

2. Ag

2

CO

3 silver carbonate

3. Ca(CN)

2 calcium cyanide

4. PbF

2 lead(II) fluoride

Work these on your own –

(but ask your partner if you need help)

Careful: I mixed in some covalent….

1. FeSO

4

2. (NH

4

)

2

CrO

4

3. NI

3

4. Fe(HCO

3

)

3

5. Co(C

2

H

3

O

2

)

3

6. Y(OH)

2

7. FeBr

3

8. SO

3

9. ZnSO

3

1. iron(II) sulfate

2. ammonium chromate

3. nitrogen triodide

4. iron (III) bicarbonate

5. Cobalt(III) acetate

6. yttrium(II) hydroxide

7. Iron(III) bromide

8. sulfur trioxide

9. zinc sulfite

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