Indo. J. Chern,
Vol. 11
NO.3
PP 201-294
Yogyakarta
November 2011
ISSN
1411-9420
INDONESIAN JOURNAL OF CHEMISTRY
Vol,11,No.3,November2011
~todbrDllmHo'~I,f)lOlf{epI2O'IO
Dor";~July2010
EdltorlnChle'
Prot, Dr, Hamo Owl Pranowo, M.SI
Email: hamodp@ugm.ac.id or
Department of Chemistry, Univers~as Gadjah Mada
Sekip Utara, Yogyakarta Indonesia 55261,TeVFax (0062·274r545188,
Webs~e : http://www.ljc.chemlstry.ullm.lc.ld
Email
:IJcullm@yahoo,com
hamopranowo@yahoo,com
Vice Editor In Chll'
Prof,Dr.Mudasir,M,En~
Drs.lqmaITahir.M.Si
Email:
Email:
mudasir@ugm.ac.id
iqmal@ugm.acJd
EdllorlalBoard
Prof. Dr. KarnaWijaya.M.Enll, (PilysicallMafarlaIChemisfry)
Prof. Dr. Jumina rOrganicChemislry)
Prof. Dr. Nuryono, MS (IncrrJanic Chemisfry)
Dr. Ria Amlunanto, M.Si. reomputetlonaVPhysical Chamistry)
Dr.TriJokoRaharjo,M.SI·rBiochemislrylBioenalysis)
Dr. Nurul HidayatAprilita(AflIliytic8VEnvironmentaIChamistry)
Advisory Editorial Board
Dr. Brian Williams (Adelaida University Australia)
Prof. Dr. DI. He. 6emdMRoda(Univels~yol
Innsbruck,Austrial
Dr.DirllBWl(Utre<;htUniverslty,Netheriands)
Prof. Dr. M.Gross(LooIsPasteurUniversity,france)
Prof. Dr. HardjonoSastrohamidjojo(Universltas
GadjahMada,lndonesfa)
Prof. Dr. David. St.C, Black (Univars1ty of New South
Wales,Australia)
Prof. Dr. MaxLu(Univers~yolQueenstand,Auslralla)
Prof. Dr. Bochori(Bandung Instiluta of Technology,
Indonesia)
Prof. Dr.AtlduIRa'ufPathon~(Ha$8nudin University,
Indonesia)
Prof. Dr. NaokiYoshioka(KeioUniverslty,Japan)
Assoc. Prof. Dr. Wan Ahmad Kamil Mahmood
(Univers~ySains Mataysia)
Administrator
Or. Akhmad Syoufian
WarakustartiLlstyartwangl,A,Md
DjokoPrlhandono
Prof. Dr. Muhammad Idil'ls Saleh (UniversitySalns
Malaysia)
DI.HeryHaenJdin(Perlamlna,lndonesia)
Proi. Dr. liplzulFalah(UnlvflrsitasGadjahMada,
Indonesia)
Prof. Sri Juari Santosa, M.Eng, Ph.D. (Universitas
GadjahMada,lr>donesia)
Prof.Or.EndanIlTnWahyuni,MS(UnlversllasGadjah
Mada,lndonesia)
Prof. Dr, Bambang Rusdiarso, DEA (Universitas Gadjah
Mada, Indonesia)
Prof.Or.WegaTnsuneryantl,M.S.,Ph.O.Eng
(Univers~asGadJahMada,lndonesla)
Prof. Dr. Sabinn Matsjeh (Univers~as Gadjah
Mada,lndonesia)
Dr. Winarto Haryadi, M,S;. (Univers~as Gadjah Mada,
Indonesia)
RobbyNoorCahyono,S.Si.,M.5c
EmieKumiawati,SH
Alms and Scope
Indonesian Joumal of Chemistry Is an Intemationel jolJlnal oovering all aspects of Chamlstry, including
Chemical Education and Chemical Engineering. The journal publishes original research papers, short
communications, and review articles. The paper published In this journal implies that the wort<; described has not
been,andwillnotbepubiishedolsawhare,exceptinabstraCl,aspartofalecture,revieworacademk:thesls.
Indonesian JrnJrnal 01 Cllemistry (ISSN,1411·9420) Is published by the Dapertment of Chamistry, Facuttyol
Mathematics and Natural Sciences, Universitas GadJsh Mada, SelUp Utara, Yogyakarta. Indonesia. All orders
ac<:ompanied by payment should be sent directly to The Department of Chemistry, Univers~as GadJah Mada.
Annual subscription rate is lOR 150,000.00 (Ja~·Ba~), IDR 200,000.00 (outside Java-Bali) (shipping Included),
~PBnm c:::e~='~t~~~J~·::r ~~I~r (~~rt~~I~~~~~' ~~fJ~~~oaJ':~~~ ~~1e;~, 'S"~~
code: BNINIDJAXXX)
I'rlDONESlAN JOURHAL OF CHEMISTRY
Yol.11,No.3,~2011
CONTENTS
S~ o.rMItlw. A ~ for NowI
-..d AntImicrobial E....lu8tlon of Some 2-(.-
olonlc:e-.~.SynttMsla,
Charac:tlriullon
t.titl/tlld AnlU.-.yndon-3·-yl)_" 3, 4-th. .INlIlO
("s.b)lnclolKbyliemilnlP_.S/liShJpalSingh.andNldhl~
~n
Eh<;t low.m
no.. Qu.llly of Cureumln lmprim.d Polymer by Em! Shlqiu Azlzl. MolId
NoorAhmlll.A.K.M.S/'IlIllqull......... OIhyarArbaln.andlqmlllT.hIr
no.. Addllion EfflCl of Sulph.nlll<: Ac:ld to tIM SynthKl. 01 3,.-.thyl.n.dloxyblnulclehyd. by
FetlF.UmahandSanuslGugu!e
Th. Actin Fr.<;tion from NlrJfI//' IItlv••nd Its Actlv1ty '1l.ln.t U7D C.ll U ... by Heny EkowaU,
EQPra$llstl,andUndrilUl.lutl
217-222
TIM Optlmlutlon of Enzymltl<: Synthesl. for lIuroyl-H_lthyl Glu<:amlcle Surf.e1.nll by
ZUMn. MuyilhtJh, seri 8lmlI Semblr1ng, ZUI Allian. and T}8hJono Herawan
Synthell.of5,7-dlhydroxy-3·...'-dlmethoxylsof\lvofromEugenolbyAndiHalrltAli'nuckln.
SIbhI~, ChairtAttww. and MUIlofi
Synthwl. ofT«plneol from ..~neM CI!I1yud by TCN'(~ItOlIt.by Nanik WijIY"d. H.m Owl
F'rInowo,.,unm,andTrtyono
-
HydrotysIsofe.t>ohydratHInCIIUYIIPulp.ndTsplo<:aFlourundlr"Ic:rowIYllrrIdlltlonby
&aHermlltl.Jo..n..idIiAnml.~~. TItIC. .so.n.ti.OnoSupamo.Ind8ln'lbfong
23&-2045
C hlrKtIlriutlon of 0.58 kb DNA StIlblnl SynthlH encoding GInI F~n1 from M11lnjo PIInt
(Gnefumgnemon)byTriJokoRatllr1o,RosyidaAzllRizkl,SII"Nom'IIIEthicII.ElyRulIlnll.IndL
2<16-252
HertlntoNugroho
TIOJ 8e1dt for PtIotOCllt.lytlc DllIr.dlItion of Humic Ac:ld In PulWltir byWlnauti And.yenl.nd
A'lu.UnNMSagyo
Pr.llmlnary Study of the Utlliutlon of lhe Fly Ash from Co.l.fl..cl Power Pr.nt for
ImmoblllZltlon of Radlo.e1I.,. W••t. by Harry Poemomo
Effie! 01 CrOl.linklng 10 IhI M.c.h.nl<:al Property of ApIIIII G.I.tin Hybrid for Bon.
Sub.lltutlonPurpo.KbySuoarao.Sulamo.KanjT$UIU.lklDe¥04Ana,andKunlol.hIkIwa
Mlorptlonof ca(ll), Pb(ll).nd Ag(l)on Sulfonlto-$lll<:a H~ p. . ...-I from RIce Hull Ash by
SiIlSuillItrl.Nuryono,I~~rtInI.""'EkoSrlKunll1l
UtIllutlon of RIce Hulk •
Su)lnllII'ldAgulKl.nalkl
RIw MIterlIl In SyntMsls of "1IOpOO"0UI Slllc:lWl Me...., by
PNpIrItIon.nd ChlIrectIrtutlon Ion SlIectIYI EII<:trode Cd(I) 8IHd on Chlt_1n f"YC
Mlmbrww by A. SefIo5I Plngglbun
NOn, A N_ Phenolic: Compound from Acetone Extnct 01 U<:hIn (lInN /lvUON T.yI. by
MIuIliyIIh.A.HerryClllyena,IndWIhyldPrtyonoS-..o
219-2&1
IrIdD,J.Chwn.,2011,ff(J),rTJ.l1'
273
ADSORPTION OF Ca(lI), Pb(ll) AND Ag(I) ON SULFONATO-SILICA HYBRID
PREPARED FROM RICE HULL ASH
Sltl Sulastrl'.1, NuryonoJ.·, Indrianll Klrtlnl', and Eko Sri Kunarti'
'St~WnlolDoctotllePro:lgram, o.{Wlmerlt 01 ChemIslIy, FKtJlfycfl.l/tlhtlma~.ro~rl,lffl/ so.lI(>f'.
UnNlIrsJt.'~Mad •. YogyWll., IIldon/lsi.
'DllplrlmllllolChlmi&lIY, FlCUlfyofMathlmalics IIld NItutaI ~s. Sla'- Ulllvef3ltyofYogya1<llrll.
~t.ng,Yogya1<llrll.llldon<JSja
·~oICMmis11y.FM:lIIryolMIthImIllicsendNMuraiSaiIonces,~'~MadI.
BI.2t.s./l¥IUtIt'a,Y~552B1,~
Rw:aived~2I5.20ff;Act;:efIted~f~2011
ABSTRACT
InIhis18seard1,.cborpIiorIoICe(If),Pb(lf)andAg("In~~onIO:~to-..siicahytorld(SSH)
~fromricelluluh(RHA)hubNnatvdifKI. TIlIpt'II»f'lJtionotSSH~W8$c:8Iriedoc.tbyolddlltion
01 metUPlrNIics /lytJrid (uSH) wiftl hydrogen petlJ16de {HzOJJ «JIution ~. MSH Wl!S prwpared, .,..
so4JeI
process, by Idding 3 U hydrochJorie Idd sohAion to mmunr 01 sodiIJm ~te (NatSiQ3l lOMion .nd
3(lrimelhoxysiJy/)-1~nlh/oi(UPTS) to 181Ch pH of 1.0. SoIlJIion of Nll:SiOs was glrllraled from deslructKx1 of
RHA wilh lSOdium hydroxide S4)/uIkIn followed with hfHlling al 500 "C for 30 mitt. TIle SSH (XOd~ was
characllrlz(J(J with Fcwrilr Ifllnsfonn Infra/'ld (FTlR) spfIdfOSlXlpy, X-ray diffraclion (XRD) .naly~." Irllfl1Y
d~ X-ray (EDX) ~llOSropy and determination or /on-Ixchange ~pecJty for $Odium ion (N.'). Thl
ttdsorptionofA'iJ(I).ndC.(I/)_l8r:onduct9dln.balch'Y3t1mi1variou'~ltalionsrrxOOllloor.The
cak;uI.l&dba(#/(lfl d~of~tIoMbef0!8sndafleradlOipOOnproceu determined
Idtott1enl ion
wa.
~ltOmicabsc<bancl~(AAS)mathod.Theadsorptionr::llaraclM'we.t1V3lUaltlduUlgfl'lO(/6/oi
lIlll~. c::MsUntsand-vtol/tdsorptirxl. RId
iMJthafmLMlgmuirandF!8UndIidrttdsorptionloClllaJlBte
oIdlanK:terizatiotllYyEDX andFTIR IhawedqualirB~/JlIISSHMi beer!.succeuA.tIy~tlizedllllflich__
bc1ieel&dbyappeannca oI~~oI~P'DI.pnamalydanol(Si-OH),IiIauM(Si-O-SIJ,
maIJIyIMa(-CHr) and~oI~P'DI.p(SH). TheXRD doIla lhawedamrxphoul.strllCtUo'eoiSSH,
. , . , to sifca gal (SG) and USH. The studyoledlorptjon ~ Ihowed ItlfII oIdd8fiQr7 of U$H Into SSH
~rhe~capacityforNa·fromO.123toO.51'tnmCllfg.ThechfJnria"'fImctionIJIgroopfrom
denoIlorrren:ap/IJ andfrommeree,oto to.wIbrNto
~
/he edIorptjon capacity 01 Ca(JI}. Howe..., /he
~orrierot~.forbolhionlolPl>(IQandAg(l)ioIaqueoWltlOhJtionilUSH"SG>SSH.
Ktywont.: ttdsrxpliOfl, silica, rica, hybrid.•ulforNJto
high yield, small proeestJng time, cost sffectlveness
Rioe twsk. !he predominanl byproducl In the milling
proceu d domestic IIIlriculture, is usualy either burned
and envltonment frienctly (3-4J. Mo$l 01 !hi soI-ge!
mllhodl [5) of prepar1rG lAS Glasa C'*WI1Ie1 are
alkOllidebased,andlhel8fore,controlofhydrolysill'lnd
Oldifeatded.resullrlgnotodrin~_ling,but
condensation ruaion of different melll alkoxide is
8110 in environmental poIulion. As e oonsequanc:e,
espadaIyin!hefleldofmaterilllsc:ienal.il.lTIlIkessense
tlt<:on'*Igd~~rd3lhetotmelionofeconvnon
natworkinwhidllhllYlrioulmetalionl_~.
lO~rieehUsknh(RHA.)...tIic:tl.OCltr\P058dof
Se-.l8ll8mptshlYebeencarriedOUlinc:llldirlg
extfemeIypu-earnorpholAsilieaextrae:ledfromrice
lTIlIIchingofhydrolysistaleBbychemicllmodifielllionl
lIIitIlehelalirlgigands.'}'I"lVlesiBoflTllAlicomponen
8Ikoxidn 01 partial prehydrotysis of a!<exIdI$ (6) •
Meehanicaly stabIa metrices, such . . dMmicalIy
mocfllltdliieaO&!surfaces, hall'll awakened growing
InllrtS1becalJSelhekncwltdgtlOOQllirtdwithlhen1
permits !he transf., 01 some propertle, found in
homogeneous chemistry to the Immobilized stalS.
Among !he more promising highly dgyeloped slirfaces
huskbyeseriesofproceuinc:U:lirlgKidIeadling.
pyroIysis,and~andmeybeusedas
.-e.toI.WCI!Itorsileltbasedrnaleriall.
InAlC8ntlimes,8OI-geImelhods[1-2)~been
considered promiUlg lor preparing llllrarw.., high purity,
.lngle and mlllli<:omponent oxidaglalll8s and ceramic
compos~.s with the advantages of high purity, lower
,Intlring temperalllre, a high degree of homogeneity,
'~-.ar.T_":'&2..v454$'N
EmoI_:nuljO'aO_mlpaGugm.ac.id
1ndo..J.ChM!..1D1f,ff/3J,Z1,.rn
274
_ltwsilca-allldledcwv~lIItllctl_wideIy
UMd fl various ted'noIogies [7-6). n- maBials
_bIe speciationdr.eeelemenbandareuseful in
toMng many ptOblems In nudear te<:hnl:*lgy,
eIIclroI'Mcs, metaIIurtlY. rnnng, medicine. 19ricu1llQ,
flIItlerielIlIIId enYironmenlalltudlM. A/Ihougtle large
*"
body of data ha,
reported aboolanchorlild ailicas.
new applications .... continuously demending further
Inlolmatfon.
Silica gel Is -.n Inorganic suppon widely ~sed in
menychemicalproeesees.lmingsevlralK:lentiflcand
tec::hnlcal applicationt (10-11). This supJlOl't has been
In<n:Jslrqy lISfId beeeuse ita surface on.. many
...... Iiica
MlUrClI.
The present RI.Idy
ems
lo
8'tIkJate1tla~dlliicamoo:lific:ltiooMh
m8l'Cllplo and S\Monalo llrouPS on lha adIorption
~usinglWOlIoIhermmodels(F~and
.....,.,,"'"
EXPERlMENTALSECTION
Precl.notoflOdiumdicata(Na,5lO,)toMionfor
IOl-geIpnx:essWMprapatedfromricehulla.sh(RHA)
~ I pn:ICIIdure reported by tb)ulo (13]. Sample d
~dullfOl~.lollsthermllandchernieal RtiA_mixlldv.tllNIOHlIOIuIion2Mlndthe
IlIlbiiulion dtRlg the 1lI81;tion proceu [1~ II has •
ritkn_~ltimldinlholplatalilcWy
Illgh-'- . . . (~m21g),lTIic::roporUliminlhe
I'1ItIQ8 5-alO 'Aand ltcantJ. used.1 rellIm.ty1ow
eottll31·SianalOf'Ol4ISOl'IslIicagel8U1_beI'I8",,1Q
• \veak IICid (pKB.g.~); It!uslheycan intefad wilh polar
c:ompoo.nd$lhroughbolhltronghydrogenbondsand
d!;)oI..-dipoleIntW8Ctlons_lt>eweUkJlQ'Ml8renlted
acid [14-151. Due to the pruenee of these groups of
adds, silica gel is .bl. to ,daofb the moll varied of
chemk;:al species such IS cyclic amlnes [16]. Ilmlde.
[1T]. proteins [18). bIoIogfcallyactivephoephates [19] •
• nd liso lor sorpllon In the S8pll11ltion prooess of the
p1alln...n metal 120], w11hout pre...o::.os modlftcation with
.n~.ThelllOlitioationollhesllicagei
lJUrr-isusuallydonebyuU1gMapproprialemolea.lle
~~qegent.iIIIll8$'~.
stablelXMlklntbond •• formed[10).~.1o
IncruN the charl can btl 0'I'III'lXlIM by Iu1Iw ~
atIClltlan_haatadlt500"Cfol"JOrni'lIn.fl.maca..
Therem..wasoi:uolvedinwaterloobtilinaoklliond
N~Thalllllg8rllgl*lad~)­
propena-l-1hiof{J.4PTS)frorn Aldridl.calioM 01 Ca(ll)•
~(I).andPb(lI)lnchlorldaandtWtrala"(greatar
1han98"'pl6ityfrornMartk),andhydroganparOllide
:mr.(Men;lc)~used.lUPPliad.
Proeaduno
Sol-pl
pI'OC8$'
for fN8PIrItJon oral/Ironlto .111c1
h,M"
Prec:ur$Qrol~lIOflltion2SmL_mO:ed
~"mlMPTSandlhanlhamixlure_lddadwilh
hydrochloridaldd3Mdropbydropand_11irTad
MJMy iii hi pH 01 7.0. The gal formed _
kept
OYWnight..-dtlen_Wllhadwilhwa.klordarto
in.AIbIequent~st8p.wIlh.v.w.tyot bafreadlddby~wilhlunlYarlalpH
orglWc fln:tions. fOIlhe many desired putpOHS. T'IlU$,
modified ••ICII is widely uMd i'l ctwm.~y(10]. lI$
aupportlcrlTlll18rialsv«thc:alalyricpropel1la(111.3S
QqI.le$Irlltion agenl 01 me18ls (211. for IorH:Jlchange
[22), abo for conlamWlants I'lIITlOYaI from waste .muent
slreem.(23],andlormanyotherpurpoHt.
InprevlousrePQrt.wade.cribedthainve.tigation.
of .~thetic schemea aiminll at the preparation of
ndlcatorpapar.Thaget_drilIdat70"ClWIdwas
groundadinto200n....nInper1idaslu.Thaproducl
obtainadwasdiclmodilllldwltllTl8'l:lp!OpfOpylgroup
(lTl8'I:Ipto lIiIica h~, MSH). The similar wOOl was
rapaatadwitlloullllOci1lonofMPTSloobtlinsiliclgel
(SG) as the control pmduct. The silica modified wilh
mercaplopropyillroupe Wall OJddozad wtth H.o. to
prodllCe sulfonic acid moieties on the,1I1ca llUrface.
orllanlo-lnorga~poI~rhybridlbyuainlllr8ditionlll
T~lIy.l.0110fMSHWlIllllUSpendedIn16mlof
heteroganeou!l rout" [241: and for lha .Mly of
aqueous 33% (wi) H.o,...mto continuout.tifring at
temparaua for 1 h [30]. The produced material
waahad MYeralti'neswithwaler..-d
elhanol and then dried at 100 "C Q'oII8m/ght. The
ttMonlclddlJOUl)lllltll(tledlolhaporlWlb-.
lJdsofptioneqlJilibriumprooanesdtladivalanlc:ations
cobllIt,nic:kal,andoopparfrorn~lOkJtion.
Homoganota rotDI IIIlng RHA 8$ the alb IOU'OIl for
prepara!ionola'Jlino.and~lI)tlrids;and
Ihe QorptIon n.Jdy d _ _ metallonl alto had been
repol'Ied[25-26J.The.-uJb:oIthl1~c:apadty
oItn.harddvalantdMtlystlOW8dhltamirloltlOltfiad
bends to IIdtorb hard base e:atIonI in higher
.-e.
Imountthatlll18l'Cll$llOmodlI'iadsiicll.
In the ~ worII .... n-tigated the adlQrPliOn
P!OC8Mn 01 ca(lI). "«!) Ind Pb(1I) in aqUllOU. lIOflltion
on.ulfonatomoditied.Hiclpreparad from rice hull a.sh
SiIi$ululriet81
room
was fi/larad,
OOl'W8l'tedi'dolOdllMTld\::loata~'Ilrough
i:lraItion 'rih NaOH IIOk.«ion (tl.l l.l~ The sold
product wu filered 0«. wahad willi dalorUad ..ner.
.-.d dMd at room tempera..... 0YlImight. The sample
_cnar.cterizadusingXRD.FT-lR~and
bydalerminlltionofCltiorH.llchlngacap-eltylnproton
(H') form.
IfIdo.J.ChMt~2011,
11(3),213-218
275
.
OCM,
H---"I;Ja<o
",.cO--J,................M•• ·-H.cO--JI~ ...
Jc"o
Jc","
..
_.I-O"~~ ~",c:OJ'~.H
JeM'
Jcllo
L
ft:7~·JHA-- ~:7~')H,o
,
,
Fig 1. RMetiofl oftullOlla!o-sHIca hybridformation •• p'. (e) fom1alion ofsiloxane borldlng; (blmlXliflcatlonofaHica
with mlreaplo group, lind (clOltidation of mllrcapm group wi1h hydrogen peroxide
spectr'o$COpy. The amount of metal Ions ItClsotbed
(~)W8Scall;::l,llaIadfromlhe~salon:
m.1C ~CJV
'Mlefe
Co
and C .... the lnitiIl IiIw:l equilibrium
c:onoItItrationofmfllallon.inmmollt...~Iy.V
IBthe¥Dlumeolthe&QUeClU' solution (LI and Mis the
--
/l\aMofadsorbem(Il)·The~~was
c.m.d out wi1h III lIIOsort:Mlnb (SO, MSH, 8Ild SSH).
Thesborptioncapacity {bl was eaIcUa:edfrom ' RESULT AND DISCUSSION
F1g2.lnfra*'lP'dJlIdproducts;siialgel(A),
men:apkl8lb H)tIrld (B) II'lCl suronam siIic8 h)Uld (e)
IaotMnrnolMlMNptlotl
The""ll;hlldsolplionmethod_usedlol'
The Ivaelion lor the kml-'lon of IItAfonal:o
I1'IOCifIedsiicaltvoughancJllflllUlfonatjonrouteis
~inFlg,'oonsistingoflhAMo~Thooe
nekldelormu\io:o'ld$lIoD~.lrameYll:W1lalailicaby
edding acid in soluIion 01 sible enloro (Fig. 1(8»'
~Ihe~ofadsofplion~lingof Immobiizallon of
100mgdadlotberJlsuspendedin50.0mLd."
lIqUMlUSmetallonlllvariousirlillillconcentrations.TIIey
W$'8mee/'lanlee.ltystlrredfor1hBlaroomtempetlllture
(298 K). The ISOkJtiona were centrifuged and the
supemeUlnt Wilt determined by atomic: abaorptlon
mlltalpto groups the si5ea <luring
formation 01 0eI (Fig. 1(b)), lIIld • CUlidnon 01 the
rnmobilizedsulfhydrytgrouPtlOlheeorre&J)Ollding
sU:!orIicacid moieties with HA,(FIg. 1(e». Experiment
wllt1 volunMltl'lcmetl\od ahowsthat in the investigated
condition oxidation of MSH to beoome SSH Increased
Indo,J.CII_.. 201',11(3),27J-118
276
.
" ...
~
eatll)
4.2014
122.0
PtJ{l1}
~
17.~
"."
"-"
m.
""
1.692
o.~
2.20
1.10
O.lIM
2.101
2.S1'
G.ne
G.lIM
2.50
1.67
2.16
1.82
0.9Il6
0.ll92
'-.-E""
-c'
. _ -- . c._
91.81
m.
t:
,-
-. .--- !:
__
::
--
0",",,
_
:t}'-
1,~
_.
. ---.-
FI1l3.Correlalioneu..... oItheamourrtof~11ons
adsorbed ....rsus concen..-atiOf'l 01 metal 1Ofl8 II
equilibrium
\he cation eJlchange capacily for
0.575mm$g.
N.·
an'"
Sl.I!llnc acid peak$ 8l 1028
PNkS 1l1095-1065
Cl)I'I'esponding to s)'lTll'l'lellie C-S slretdWlg
em"
V1~Iions.peakaat960-950an·'fof8S)IM'lIllJir:e-s
strelC:hing.~peak$at1028,,2S(.8nd1084an-'for
S:O slrelching camet be dislingu\$hed Irom !he broad
and strong siIoxane absofption lINk because of the
overIappingofbilndsf28J.~,lhereI8~Y9
Inaease oIlhe intensity oflhe h~)()'t n.nd freQuency
belwllen3200and3400cn,.'lrtdltledis.appearanceof
l!le weak -$H peak II 2580 a11" indlclllol thai the
IWlfonation reaCliOn had indeedoccurr&d,with the
eubsequentoxJdalionof_SHgrOUPllo_SO.Hgroups
From the x_ray diffraction pattem (data is not
dIOwn), three produeu (SG, MSH .nd SSH). thai are
almllar to !hose reported eyei')Where. show a broad
peak with maximum intenlity .round 29 • 21-23'.
Acoording to Kalaphatyetal. 129],slllca wilh the wide
band and the maximum peak al 29 • 20-22" is
characteristic of silica for..-norpl'loul structure.
Thereby. resun d dIarltctariudon with XRD males
lhatmodiricationdlilicawithbolhmarcaptoand
suffonalogroupsdonotcaull8lhedlangeollhesiiea
from 0.123 to
"""'"~.
Adsorption I$ott-m
Ptlp"-'l~ofp<'Odloc:ts
Toi'lYestigateltleadaorplioncapac:ity,Yarious
InfIowedlf*holl!Hlproduc:tslllvanou.tttga;
oIit1modilie:etionby ... SlAfonatillnrudiotl ......
pefbmt<ltomonitDrctlangesonilssuf. . (Fig.2).
Siicllgeiltidentifledlllffilhlprua"lC8ofsp«:ifte
spedI1IoIstrell:tlirllYibr.rliooIrom--OHlromeilanol
oor'iC*"lll'3titnsdc.e:II),Pb(.)andAQ(I)~were
llimodfot1hwithadsorbenl8lrooml8r'np8t'8t1n.The
uparimant data is axprllll8d in fig. 3 as CU~
~lheamoo..ntofmefalonsac!lolbedYel'Sl.ll
eoncentrr.ion of metal
Ions 81 8Ql.illbrUn. For
group(3425c:m·').8endingvitntionotr.atgroup
inIerpretationollheadMlfPlionuperirnentaldala,1WO
~""11636en"'.Spectnl811080.nd795o:m·' iIotMrm {langmuir and Freundlicto) rnoc:IaIa_e US«!
OOIMS from strekftng and bending YibnlliON,
[3O].The~llSIionofIheUongrnu"modells:
respeetiveIy,oISl-OlromsioXane($i-O-Si).Tl'le
m·1b.~
presenee of Ihe mereaptopropyt WOUP' In Ihe
Mu:tiOl'lloll:ed material Wilsevidenced by the presenc:e
where m is the lI!Tlounl of melal ionl adaortlec!
ofstrongC-l-lllJelehlngWlnilionsoflhepropyldl.IM,t
(mmolfg)llIequilibltum:Cialtleconoanlrlltionofmetal
29OOcm·'127}.nd._kYibratioo<XlfT'8spondlngtoltll
Ionlelequilibrium:l(represenl$theLang.muireon
-5H groop .12580 em", Nlndicated In Fill. 2. fOfIhe
(Ummol) thai retatea to the affinity of twldlrIQ lites.,;:
sulton.lion reaction. thl Itllol groups In the MSH Wilr8
oxidized by HIOl to sulfonic acid unl1$. How1!v.r,
SiliSulastrlelal.
blsthfltheoreticall8lun1tionadlJOf'?lioncapacityd
monolayer (mmollg).
277
.... COI'IC:Uiondrewnfromtheprlllft..lIJdYls1tllll:1NI:
slMonItionroutllcanMIIIJ"iZedfa"lheg_rationot
~ic:roonic)PfOPllItYotadsorbentSlJ~.
lmpr'oYementoftllelonlcpropertyleelsoexpecledto
M .bl. to incrll8H euloes.s In desorblng metal ionI
adsorbed, 8S weH '1, IIntlanQ!l ttle reversibility of
~Kfleltl.F"'lmdlichoonslantrelotedto.dlOfplion adsorbent
eepeeityofltdlOl1>tnllW'dnletlMoF...oo(Hjch~
m_K,C"
NllIl8dto~inlenUy.K.andneenM ACKNOWLEDGEM!HT
eab.Ul8dfn:m\he . . andrurceptolh ...... ~
aflDllm ...... 1Dll
Tllble2ci1playtlhecoef!ldwlttol
c.
:':..=-~~ fl'lOd«5
IIlong WIll
MUM from T.ble 1.1he R'VlIIUlllI forboll'lthe
_ _ moetly
.!loYeO.90,wggMtingflBlbothmodelsc::loMlyfilthe
l»lperlmental
~.Theltdsorptioncapacityoft~
monolllyer(b)
lues for~(ll) on .dsorbents was In
order. sa > SSH > MSH. Till. fact can be ex,pl.llned
1,l.1rlg haI'd acid PfOPllItYoIClI(II)'nd .i19actlv8. 01 the
~andFtewldlichisottwmmodels
8Cbofbents.Addlbafmen:;aptogroupsk)tIMo~iClI
~ the ~ of the Qorbent. Htlnce. the
~afC8(lI)lllnterllel\/lliltlmen:aplOgroups
~ .. -ak. ~ , by 0lCIdri0n proceu leltd"~
III bmIIb 01 U'onaIo (-5O)H) the twd_ af
~ . W n ~.00 . . eepdyill ncruMd,M
...... DilhnntphenomenaOClCUlonsoftmetalloNaf
Wethar*-hlGmerlIlor.c:torafHghet
EduCilb,Republcol~hOIIghnlSean::n
grwltIHilahKampe**Z011fa"flnenciafllJpporI,
.., LV. Simmll)llng end E.Y.W. Hebibl fa" ...
_ _nee In collecting upermentdalll.
REFERENCES
,.
Wang, B.. SZll, S., Greenblatl, M., and Klein, L.,
1992, Chem. Mat.,., 4, 191-197.
2. ~'~,u130\~:,andJi;an,C.,l995.
3.
4.
Nqg-. M.K, ~, M., and Dey. A, Ind.
Patlllllepplicalion No. 127M)EUl)1, 2001.
NuQ-, ILK, end CMtterjIIII. IL, 2004, J. EiJr.
Qltem.Soc..24,349i-3508.
Aq(1)~Pb(lI).\O'llhtheaimi"reepeeityV8lueorderfa"
5. ~Y.,~'990~'';'':1~~~.end
two tlrJI ~sorbents (80 "
6.
MSH). However, the Increase
ral,l~ is
Ilmllarto thllprevlo\lson8repol'\8d[26j.Ttlachangaof
IKeactivesfrornmen:apIDtolWlfonalobyoldd.lion
of eepecity for Ag(I) Ie tllgtler th,n Pb(1i} and this
1Nd•.to dBdll'l8 the IIdsorption eIf4)8CiliIIs.lt is dearlhat
oxId8tionQ!lUMIlmproYtllTlelllafl'lydroptUcpropertyof
7.
Eeql,lena, J., and Solans, C.. 2001, CoNoid8 Surl"
8.
;:~RF:f:~'~~'R.~~~en~~,J'6::
A, 180,65-92
~l,J.
8deortIent'llQch.irIl1in11witl"~1ll8deolb
IlardmetalloN.lfthe8d5orplloneapaQtyYN.IMoi
~. . . onieroi
Ag(l)-Pb(II) >C8(1l) ilotlIaIn«l• • • prob8bIydlJe to
~~:'~.~.~i.,R,'990,J.
CoIoi::fhll'fft-Sd,241, 1.45-51.
~~a:~;5~\t~~:
tlnemetallcqonSSH . .
i.
IhebondingtweolCa(ll)roonic)endlncom~of
10.ArIbld,LN.H.,8ndAiroldi,C.,2000,~,
OICIdBIion..lonicbond mByM rHC!ytobebrol<endownin
lIqIJeOIJS(po!ar)lOkIIionvi'soIvetionand\he1,ll"\o
oxidized mereaptOgroups ntaract'ft1lh Ag(I) and Pb(II)
bBtterlhan'NithC.(Ii).
19,4,367-373.
11.:=: MM,. S=::nA.,Y.~~~:,
~:l~~~.J . 1998,
Soc.
Bull. Chem.
~'~
Jpn., 71,
Ch8mleII ..... modiIcrioroisusedwldfllylo
otQintheo.lnld propertiM and perfoImanoe 01
tl'llWiU.ln"pr'III8JIIIs:tu:ty,thecNmical(llIJonato)
12.Wlllon,K,andCl.r1c.J.H., 1998,J. Chem. Soc..
Chern. Commun., 19, 2135-2136.
13. Price. P.M.• CIer1l.. J.H., and MaajuarriII, D.J.,
2OOO.J.Chem.Sor;.o.ItonT...... 2,'01-110.
14. AkokI, c.,.., de F.nas, RE., 2000, Quin. Nan,
~~-=~~~=
15.~~~~~N~,~
CONCLUSION
dMrtyirllil:n . . suc:cesstul . . . . . rnodifIcItionaf
dcaparticlM.ThernGlftl6d~bumg\he
Il,lronal8dmolety.ndt~praIeO<:8ofthe1'llnctlone1
groupstladno.tfectont~.truetJrllotsJlica.Hen<:e,
23,1,496--603.
303.
16·=,~~~70nd0n~.andlnterflce$,
1ndo.J.Ctt.ft.1Of1, ""),27:1.27.
278
17. L)'lIin, V.L. 1994, KiHtt. K.ta. 35. ot8O.
18. 8IAtewskl. 8., Jezilnb, M.. Weriak. M.. and
e.r.k, D., 1998. J. Hif1h RHcAL Chroma/OV·, 21,
HcJIA&hfrxHNvy~JonAdsotptJon,
PrftenledallntemillionalConlereneedChen*:lol
sa.nc:.(ICCS)Heldby~ofCherrlistty.
~ Ga48h M.o. WId Sd'lool ofCherniRy.
LnYwIili Sains Ma"'yN 01'124-25 May 2001, In
Yogyakartl,n:Ionesla
2O.r".T.,Eriguehl,E.,Ft,f.M.. W.tanabe,T.,and
26.Nuryono.~.E.N.,TtiIarIono,L
.• end
Narsito, 2007, Adso<ptJoo 01 Huvy MIltllllcnr 0l'I
CI'IilW:8wa.M.,1998.~Acta,308.1.
139-145.
~HybridPrwptJ18dh'Qm~H~
21. 0IYelnI, S.F., Esp(nolII, J.G.P., Lemus. W.E.S.. de
A.$Il,PresentedOnillyonlntemalionalCOnf_1'I08
SouU,A.G.. llndAiroldi,C., 1998,CcIoids$l.Jrf.,A,
end WOl1lshop on Batie end AppUed Sden<:ell
136,151-154
UNAIR·RUG- KNAW-VTM, 6-7 August 2007
5,267-281.
19. 1uNlI. H.M., Monscu, SAA..
n
bid, M.I., 1992.
~AlD,202,269-280.
22. Butterworth,A.J.. Clllr1<,J.H., W.IIQl1, P.H .• Barlow.
S.J., 1996, J. Chern. Soc.. Chern. Ccmmun.• 27. 48.
1859-1860.
23. Prlce, P.M., Clark. J.I-I.. lind MilCqUllme, D.J.. 2Ql0.
J. Chem. Soc. Dalfon TratI$.. 101-110.
24. Azm/y8W8ti. C., Narsilo, .nd
ChlJm..
Nuryooo. 2005. Indo. J.
5,1.31~5.
25.~s;:'~'~~~"=
27. Shylesh,S., Sharma, S" Mirlljkar, S.P., and Singh,
A.P.. 2004, J. Mol. Cal." A: Chern., 212, 219-228.
28, lIu, S.. and Chen, T., 2001, Polymer, 42, 1, 32933296.
29. Kalapalhy, U., Proetor, A., and Schultz, J., 2000,
BiOI'UOUT.T&<:hnol.. 73,257-262.
30. ~mesh, A., Hasegawa, H., Sugimolo, W.• MaId.
T.,..cI Ueda. K. 2008, Bior'$-.-. TfIdJnd.. eg.
3801-3809.