```13-34
13-60 The volume fractions of components of a gas mixture during the expansion process of the ideal Otto cycle are given.
The thermal efficiency of this cycle is to be determined.
Assumptions All gases will be modeled as ideal gases with constant specific heats.
Properties The molar masses of N2, O2, H2O, and CO2 are 28.0, 32.0, 18.0, and 44.0 kg/kmol, respectively (Table A-1).
The constant-pressure specific heats of these gases at room temperature are 1.039, 0.918, 1.8723, and 0.846 kJ/kgK,
respectively. The air properties at room temperature are cp = 1.005 kJ/kgK, cv = 0.718 kJ/kgK, k = 1.4 (Table A-2a).
Analysis We consider 100 kmol of this mixture. Noting that volume fractions are equal to the mole fractions, mass of each
component are
m N2  N N2 M N2  (30 kmol)(28 kg/kmol)  840 kg
m O2  N O2 M O2  (10 kmol)(32 kg/kmol)  320 kg
30% N2
10% O2
35% H2O
25% CO2
(by volume)
m H2O  N H2O M H2O  (35 kmol)(18 kg/kmol)  630 kg
m CO2  N CO2 M CO2  (25 kmol)(44 kg/kmol)  1100 kg
The total mass is
m m  m N2  m O2  m H2O  m CO2
 840  320  630  1100
 2890 kg
Then the mass fractions are
mf N2 
P
m N2
840 kg

 0.2907
mm
2890 kg
mf O2 
m O2
320 kg

 0.1107
mm
2890 kg
mf H2O 
m H2O
630 kg

 0.2180
mm
2890 kg
mf CO2 
m CO2 1100 kg

 0.3806
mm
2890 kg
3
4
2
1
v
The constant-pressure specific heat of the mixture is determined from
c p  mf N2 c p , N2  mf O2 c p ,O2  mf H2O c p , H2O  mf CO2 c p ,CO2
 0.2907  1.039  0.1107  0.918  0.2180  1.8723  0.3806  0.846
 1.134 kJ/kg  K
The apparent molecular weight of the mixture is
Mm 
mm
2890 kg

 28.90 kg/kmol
N m 100 kmol
The apparent gas constant of the mixture is
R
Ru
8.314 kJ/kmol  K

 0.2877 kJ/kg  K
28.90 kg/kmol
Mm
Then the constant-volume specific heat is
cv  c p  R  1.134  0.2877  0.846 kJ/kg  K
The specific heat ratio is
k
cp
cv

1.134
 1.340
0.846
The average of the air properties at room temperature and combustion gas properties are
PROPRIETARY MATERIAL. © 2011 The McGraw-Hill Companies, Inc. Limited distribution permitted only to teachers and educators for course
preparation. If you are a student using this Manual, you are using it without permission.
13-35
c p ,avg  0.5(1.134  1.005)  1.070 kJ/kg  K
cv ,avg  0.5(0.846  0.718)  0.782 kJ/kg  K
k avg  0.5(1.34  1.4)  1.37
These average properties will be used for heat addition and rejection processes. For compression, the air properties at room
temperature and during expansion, the mixture properties will be used. During the compression process,
T2  T1 r k 1  (288 K )(8) 0.4  662 K
q in  cv ,avg (T3  T2 )  (0.782 kJ/kg  K )(1373  662) K  556 kJ/kg
During the expansion process,
1
T4  T3  
r
k 1
1
 (1373 K ) 
8
0.37
 636.1 K
During the heat rejection process,
q out  cv ,avg (T4  T1 )  (0.782 kJ/kg  K )(636.1  288) K  272.2 kJ/kg
The thermal efficiency of the cycle is then
 th  1 
q out
272.2 kJ/kg
 1
 0.511
556 kJ/kg
q in
PROPRIETARY MATERIAL. © 2011 The McGraw-Hill Companies, Inc. Limited distribution permitted only to teachers and educators for course
preparation. If you are a student using this Manual, you are using it without permission.
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