GAF Safety Data Sheet SDS # 3061 SDS Date: November 2015

advertisement
GAF
Safety Data Sheet
SDS # 3061
SDS Date: November 2015
_________________________________________________________________________
SECTION 1: PRODUCT AND COMPANY INFORMATION
PRODUCT NAME:
United Coatings Hydrostop Knockdown Texture Cement
TRADE NAME:
N/A
CHEMICAL NAME /
SYNONYM:
N/A
MANUFACTURER:
GAF
1 Campus Drive, Parsippany, NJ 07054
ADDRESS:
24-HOUR EMERGENCY
PHONE (CHEMTREC):
800 – 424 – 9300
INFORMATION ONLY:
800 – 766 – 3411
PREPARED BY:
Corporate EHS
APPROVED BY:
Corporate EHS
SECTION 2: HAZARD IDENTIFICATION
NFPA and HMIS RATINGS:
NFPA Hazard
Rating
HMIS Hazard
Rating
Health
1
Flammable
Reactive
1
0
0
Reactive
0
0
Special Hazards
-
Personal Protection
X
Health
Flammable
GHS LABEL ELEMENTS:
GHS CLASSIFICATION:
Eye Irritant - Category 1
Skin Irritant - Category 1
Target Organ (SE) - Category 3
Carcinogen – Category 1
Page 1 of 7
GAF
SDS # 3061
GHS PICTOGRAMS:
SIGNAL WORD:
HAZARD
STATEMENTS:
Danger
Causes sever skin burns
Causes serious eye irritation
Harmful if inhaled
May cause cancer
ADDITIONAL HAZARD IDENTIFICATION INFORMATION:
PRIMARY ROUTE OF EXPOSURE:
Inhalation, Ingestion, Skin contact
SIGNS & SYMPTONS OF EXPOSURE
EYES:
May cause severe eye irritation.
SKIN:
Can cause severe skin burns.
INGESTION:
Harmful if swallowed.
INHALATION:
May cause respiratory irritation.
ACUTE HEALTH HAZARDS:
See above.
Dusts from this product, when combined with water or sweat,
produce a corrosive alkaline solution.
CHRONIC HEALTH HAZARDS:
Prolonged and repeated breathing of dust may cause lung disease.
The extent and severity of lung injury correlates with the length of
exposure and dust concentration. Inflammation of the respiratory
passages, ulceration and perforation of the nasal septum and
pneumonia has been attributed to the inhalation of dust containing
calcium oxide. Contains crystalline silica. Long-term exposure to
fine airborne crystalline silica dust may cause silicosis a form of
pulmonary fibrosis that can cause shortness of breath, cough and
reduced lung function. Particles with diameters less than 1
micrometer are considered most hazardous.
CARCINOGENICITY:
Portland cement is not classifiable as a human carcinogen.
Crystalline silica is considered a hazard by inhalation. IARC has
classified crystalline silica as a Group 1 substance, carcinogenic to
humans. This classification is based on the findings of laboratory
animal studies (inhalation and implantation) and epidemiology
studies that were considered sufficient for carcinogenicity.
Page 2 of 7
GAF
SDS # 3061
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
OCCUPATIONAL EXPOSURE LIMITS
CHEMICAL NAME
Portland cement
CAS #
%
OSHA
ACGIH
OTHER
65977-15-1
75
15 mg/m3 (total dust)
5 mg/m3 (respirable)
NE
1.0 mg/m3
NE
NE
NE
Non-Hazardous
Ingredients
25
NE = Not Established
SECTION 4: FIRST AID MEASRURES
FIRST AID PROCEDURES
EYES:
After initial flushing, remove any contact lenses and continue flushing for
at least 15 minutes. Get immediate medical attention.
SKIN:
Remove contaminated clothing and shoes. Immediately wash exposed
area with soap and water. Get medical attention immediately.
INHALATION:
Move individual away from exposure and into fresh air. If not breathing,
give artificial respiration. Get immediate medical attention.
INGESTION:
If swallowed, immediately give 2 glasses of water. Do not induce
vomiting. Contact a physician. Never give anything by mouth to an
unconscious person. Get immediate medical attention.
NOTES TO PHYSICIANS OR
FIRST AID PROVIDERS:
Care should be supportive and treatment should be based on the
judgment of the physician in response to the action of the patient.
SECTION 5: FIRE FIGHTING PROCEDURES
SUITABLE EXTINGUISHING MEDIA:
Water, Carbon dioxide, foam or Dry chemical
HAZARDOUS COMBUSTION
PRODUCTS:
Carbon dioxide and Carbon Monoxide.
RECOMMENDED FIRE FIGHTING
PROCEDURES:
Wear full firefighting turn-out gear (full Bunker gear), and
respiratory protection (SCBA).
UNUSUAL FIRE & EXPLOSION
HAZARDS:
Reacts with water to form carbon dioxide gas, which may
create excessive pressure in containers. At temperatures
greater than 400o F material may polymerize causing pressure
build up in closed containers. Explosive rupture is possible.
Use cold water to cool containers exposed to fire. Reacts
Page 3 of 7
GAF
SDS # 3061
exothermically with polyol and alcohols. Reacts exothermically
and possibly violently with acids, amines, and alkaline
solutions.
SECTION 6: ACCIDENTAL RELEASE MEASURES
ACCIDENTAL RELEASE MEASURES:
Evacuate non-emergency personnel to a safe area. Stop spill at
source, dike area of spill to prevent spreading. Absorb spill with
inert material such as dry sand or earth and place in a chemical
waste container. Neutralize spill with mixture of 90% water, 3-8%
ammonia and 2-7% detergent. Add at a 10 to 1 ratio and let stand
for 48 hrs allowing CO2 to escape.
SECTION 7: HANDLING AND STORAGE
HANDLING AND STORAGE:
Avoid extreme temperatures. Keep container closed when not in
use. Store in a cool dry place, (50o F – 90.1o F).
OTHER PRECAUTIONS:
None.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS /
VENTILATION:
Facilities storing or utilizing this material should be equipped with
an eyewash and safety shower. Use process enclosures, local
exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits.
RESPIRATORY PROTECTION:
If workplace exposure limit(s) of product or any component is
exceeded, a NIOSH-approved respirator is advised in absence of
proper environmental control. Engineering or administrative
controls should be implemented to reduce exposure.
EYE PROTECTION:
Safety glasses should be worn.
SKIN PROTECTION:
Avoid contact with skin. Selection of specific PPE such as boots,
gloves, aprons, and full body suit will depend on operation.
OTHER PROTECTIVE EQUIPMENT:
N/A
WORK HYGIENIC PRACTICES:
N/A
Page 4 of 7
GAF
SDS # 3061
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE & ODOR:
Gray or white powder
FLASH POINT:
Not Applicable
LOWER EXPLOSIVE LIMIT:
Not Applicable
COC
UPPER EXPLOSIVE LIMIT:
Not Applicable
METHOD USED:
EVAPORATION RATE:
No data
BOILING POINT:
Not Applicable
pH (undiluted product):
10-12
MELTING POINT:
Not Applicable
SOLUBILITY IN WATER:
Reacts with Water
No data
VAPOR DENSITY:
VAPOR PRESSURE:
Not Applicable
No data
VOC WITH WATER (LBS/GAL):
3.15 (Water = 1)
SPECIFIC GRAVITY:
PERCENT VOLATILE:
No data
MOLECULAR WEIGHT:
No data
WITHOUT WATER (LBS/GAL):
No data
SECTION 10: STABILITY AND REACTIVITY
THERMAL STABILITY:
STABLE X
UNSTABLE
CONDITIONS TO AVOID (STABILITY):
Avoid moisture, acids, aluminum.
INCOMPATIBILITY (MATERIAL TO
AVOID):
Strong acids - Incompatible with strong acids; may react
vigorously.
Water - reaction generates heat.
Aluminum – Aluminum powder and other alkali earth elements
will react in the presence of water liberating extremely
flammable hydrogen gas. Calcium oxide is corrosive to
aluminum metal.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS:
Reacts slowly with water forming hydrated compounds,
releasing heat and a strongly alkaline solution.
HAZARDOUS POLYMERIZATION:
Will not occur.
_________________________________________________________________________________________
SECTION 11: TOXICOLOGICAL INFORMATION
TOXICOLOGICAL
INFORMATION:
Not Available
Page 5 of 7
GAF
SDS # 3061
SECTION 12: ECOLOGICAL INFORMATION
Harmful to aquatic life. Contact with water forms an alkaline solution.
Avoid release to the environment.
Data for Calcium oxide:
96 hour LC50 freshwater fish Cyprinus carpio = 1 070 mg/L (static).
Chronic 46 day NOEC freshwater fish Oreochromis niloticus
juvenile(fledgling, hatchling, weanling)= 100 mg/L
ECOLOGICAL INFORMATION:
_________________________________________________________________________________________
SECTION 13: DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD:
This product, as supplied, is not regulated as a hazardous waste by the
U.S. Environmental Protection Agency (EPA) under Resource
Conservation and Recovery Act (RCRA) regulations. Comply with state
and local regulations for disposal.
RCRA HAZARD CLASS:
None.
SECTION 14: TRANSPORTATION INFORMATION
U.S. DOT TRANSPORTATION
PROPER SHIPPING NAME:
N/A
HAZARD CLASS:
N/A
ID NUMBER:
N/A
PACKING GROUP:
N/A
LABEL STATEMENT:
N/A
OTHER:
N/A
SECTION 15: REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS
TSCA:
This product and its components are listed on the TSCA 8(b)
inventory.
CERCLA:
Not Applicable.
Page 6 of 7
GAF
SDS # 3061
SARA
311 / 312 HAZARD CATEGORIES:
Not Applicable.
313 REPORTABLE INGREDIENTS:
Not Applicable.
CALIFORNIA PROPOSITION 65:
This product contains a chemical known to the state of California to
cause cancer and birth defects, or other reproductive harm.
SECTION 16: OTHER INFORMATION
ADDITIONAL COMMENTS:
N/A
DATE OF PREVIOUS SDS:
New SDS
CHANGES SINCE PREVIOUS SDS:
Conversion to GAF SDS.
This information relates to the specific material designated and may not be valid for such material used
on combination with any other materials or in any process. Such information is to the best of our
knowledge and belief accurate and reliable as of the date compiled. However, no representation,
warranty or guarantee, expressed or implied, is made as to its accuracy, reliability, or completeness. It
is the user’s responsibility to satisfy himself as to the suitability and completeness of such information
for his particular use. We do not accept liability for any loss or damage that may occur from the use of
this information. Nothing herein shall be construed as a recommendation for uses which infringe valid
patents or as extending a license of valid patents.
Page 7 of 7
Download